Evidence for Er3+⇌Tm3+ energy transfers in cadmium fluoride crystals
Identifieur interne : 000E93 ( Main/Exploration ); précédent : 000E92; suivant : 000E94Evidence for Er3+⇌Tm3+ energy transfers in cadmium fluoride crystals
Auteurs : J.P. Jouart [France]Source :
- Journal of Luminescence [ 0022-2313 ] ; 1980.
Abstract
This paper describes the results of an investigation of energy transfers between Er3+ and Tm3+ ions in cadmium fluoride crystals. Four non-radiative transfers which play an important role in the infrared conversion processes are presented. For the first time, we report Er3+→Tm3+→Er3+ transfers which explain how the Tm3+ acts as the sensitizer of the red fluorescence of Er3+. The study of energy transfer by measurements of the anti-Stokes fluorescence intensity is shown to be a useful method to clarify the excitation mechanisms of rare-earth ions.
Url:
DOI: 10.1016/0022-2313(80)90015-0
Affiliations:
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<front><div type="abstract" xml:lang="en">This paper describes the results of an investigation of energy transfers between Er3+ and Tm3+ ions in cadmium fluoride crystals. Four non-radiative transfers which play an important role in the infrared conversion processes are presented. For the first time, we report Er3+→Tm3+→Er3+ transfers which explain how the Tm3+ acts as the sensitizer of the red fluorescence of Er3+. The study of energy transfer by measurements of the anti-Stokes fluorescence intensity is shown to be a useful method to clarify the excitation mechanisms of rare-earth ions.</div>
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